1-3-1 親金相互作用36-412 つの金原子同士が3.6 Å 以下

1-3-1 親金相互作用36-41
2 つの金原子同士が3.6 Å 以下の距離に接近すると5 つの5d 軌道のうち，5dz
2
軌道が重なり，結合性軌道（σ）と反結合性軌道（σ*）に分裂する36-39。しかし
金(I)イオンなどのd10 金属イオンは，5d 軌道が電子で完全に満たされているため，
金属イオン同士の接近による5d 軌道同士の相互作用によって新たに結合性軌道
と反結合性軌道が生じても，その全てが電子で満たされることになり，結合性
の相互作用は生じない。また，この軌道よりもエネルギーの高い6s 軌道，6p 軌
道も金属イオンの接近により結合性軌道と反結合性軌道が生じるが，これらは
完全に空位であるため結合性の相互作用は生じない。しかし，これら複数の軌
道の重なりにより形成された分子軌道の中に同じ対称性の軌道が存在すると，
それらは互いに配置間相互作用と呼ばれる相互作用を形成する。この配置間相
互作用によって，エネルギー的に低い軌道はより安定化し，高い軌道はその分
だけ不安定化することで，親金相互作用と呼ばれる分子間相互作用が生じる（図
1-3）36。この

ผลลัพธ์ (อังกฤษ) 1:

1-3-1 parent money mutual action 36-41Approaching the distance of less than 3.6 a. KANEHARA children between two and five 5 d orbital of 5 dz236-39, split (σ) orbitals and orbitals antibonding (σ *) orbital overlap. However,For d10 metal ions such as gold (I) Ion, 5 d trajectory is completely filled with electrons,With new interactions between metal ions with 5 d orbital bonding orbitalsAnd means even if the antibonding orbitals that everything is filled with electronic connectivityOf the interactions. In addition, this orbit higher than the energy of 6 s orbit, 6 p gaugeWay cause due to the approach of the metal ions bonding orbitals and orbitals, but these areFor the complete vacancy no bonding interaction. However, these multiple gaugeIn a molecular orbital formed by the overlap of the road has the same symmetry orbit, andThey form interaction is called the configuration interaction with each other. This deployment phaseMore energy in low orbit by the hyperfine interaction, and stabilization, high trajectory pmOnly in the parent is called gold interactions and Intermolecular interactions (Figure1-3) 36. This

ผลลัพธ์ (อังกฤษ) 2:

1-3-1 Oya-kin interaction 36-41
two gold atoms together is 3.6 Å of the following to and five 5d orbit close to the distance, 5Dz
2
overlap orbit, anti-bonding orbital and bonding orbital (σ) 36-39 which splits into (σ *). But
gold (I) d10 metal ions such as ions, since the 5d orbit is completely filled with electrons,
new bonding orbital by the interaction of the 5d orbit each other due to the proximity of metal ions to each other
and the anti-bonding orbital Even occur, it means that all of which are filled with electrons, the binding
does not occur interactions. In addition, high 6s orbital energy than this track, 6p軌
road is also occur bonding orbital and anti-bonding orbital by the approach of the metal ion, these
do not occur interaction of binding because it is completely vacant. However, the plurality of軌
the same symmetry orbit in a molecular orbital formed by overlap of roads exist,
they form an interaction called configuration interaction with one another. This arrangement between phase
by for interaction, energetically low orbit is more stable, high trajectory that amount
be to destabilize only, intermolecular interaction called Oya-kin interaction occurs (Figure
1-3) 36 . This

ผลลัพธ์ (อังกฤษ) 3:

Five (5) is one of the two d orbitals ， 1-3-1 aurophilic interactions between 36 and 41 at the gold atoms close to or less than the distance of 3.6 ang ， 5 DZ 2 orbital bonding orbital overlap (σ) and the antibonding orbital splitting in the range (. Sigma. 36. But at the I gold. ， d10 metal ions such as ion 5 d orbital electron is fully filled with the metal ion in the coming 5 mmeans the d orbitals and orbital interactions at the bonding and antibonding orbital caused by ， becomes a new ， to be filled with the electron binding at allThe resulting from the interaction. Further than this ， 6S orbital orbital energy ， ， P Rail Road 6 metal ions caused by approach of orbit for these occur at the vacancy is completely not binding interactions. However, they have the same ， mmeans orbital symmetry of molecular orbital is formed by overlapping a plurality of rail way at present, and to form an interaction called interact with each other and are arranged between the. By ， phase at this configuration interactionThe orbital energy is lower than the ， stabilized high orbit to ， instability that only occurs at the molecular interactions between parents and money called interaction (Fig. 1). This