1-3-1 Oya-kin interaction 36-41
two gold atoms together is 3.6 Å of the following to and five 5d orbit close to the distance, 5Dz
2
overlap orbit, anti-bonding orbital and bonding orbital (σ) 36-39 which splits into (σ *). But
gold (I) d10 metal ions such as ions, since the 5d orbit is completely filled with electrons,
new bonding orbital by the interaction of the 5d orbit each other due to the proximity of metal ions to each other
and the anti-bonding orbital Even occur, it means that all of which are filled with electrons, the binding
does not occur interactions. In addition, high 6s orbital energy than this track, 6p軌
road is also occur bonding orbital and anti-bonding orbital by the approach of the metal ion, these
do not occur interaction of binding because it is completely vacant. However, the plurality of軌
the same symmetry orbit in a molecular orbital formed by overlap of roads exist,
they form an interaction called configuration interaction with one another. This arrangement between phase
by for interaction, energetically low orbit is more stable, high trajectory that amount
be to destabilize only, intermolecular interaction called Oya-kin interaction occurs (Figure
1-3) 36 . This
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