we present
a study on T49 [bis(4-(9-(4-((4-cyanobenzoyl)oxy)phenyl)nonyl)-
phenyl) 4,4’-(nonane-1,9-diyl)dibenzoate], a liquid-crystalline
oligomer exhibiting the twist-bend nematic phase, which has
a molecular length that is of comparable dimensions to the
sub-10 nm pitch determined for CB9CB, and provide new insights
into the differentiation between the nano- and macroscience
for self-assembling supermolecular systems.