合成した棒状金錯体の分子構造と結晶相における凝集構造を確認するため，各

合成した棒状金錯体の分子構造と結晶相における凝集構造を確認するため，
各錯体（A-Bi6, Rac-Bi6 , S-Nap6）の単結晶X 線構造解析を行った。S-Ph6 とS-Bi6
は単結晶が得られなかったため，解析を行うことができなかった。得られた各
錯体の凝集構造を図2-2 に，結晶学的データを表2-1 に示す。本研究室で合成し
たA-Ph664 とA-Nap667 の解析結果もあわせて示す。
キラルな錯体S-Nap6 は重原子法を用いた解析を行い，絶対構造を決定した。
その結果，得られた分子構造よりS-Nap6 はS 体であると判断した。

ผลลัพธ์ (อังกฤษ) 1:

To determine the molecular structures of rod-shaped gold complexes were synthesized and structure in the crystalline phase,Single crystal X-ray structural analysis each complexes (A-Bi6, Rac-Bi6, S-Nap6). S-Ph6 and S-Bi6Has failed to do the analysis did not obtain the Crystal. Each resultingAggregation structure of complexes in Figure 2-2, crystallographic data indicate in table 2-1. Our laboratory is achieved withWe show the results were A-Ph664 and A-Nap667.S-Nap6 complexes of Chiral analysis using the heavy-Atom method, determining the absolute structure.As a result, the resulting molecular structure than S-Nap6 S body with the judge.

ผลลัพธ์ (อังกฤษ) 2:

In order to confirm the synthesized molecular structure of the rod-shaped gold complex aggregation structure in the crystal phase,
it was single-crystal X-ray structure analysis of each complex (A-Bi6, Rac-Bi6, S-Nap6). S-Ph6 and S-Bi6
for a single crystal can not be obtained, it was not possible to perform the analysis. Each obtained
the aggregation structure of the complex in Figure 2-2, it shows the crystallographic data in Table 2-1. Were synthesized in this laboratory
analysis results of the A-Ph664 and A-Nap667 was also shown.
Chiral complexes S-Nap6 performs analysis using the heavy atom method, we determined the absolute structure.
As a result, the S-Nap6 from the resulting molecular structure it is determined to be the S-isomer.

ผลลัพธ์ (อังกฤษ) 3:

In order to make sure the complex 3h-prolin aggregation structure in crystalline phase and molecular structure of synthesized gold complexes (A -- 6 -- 6 Bi, Rac Bi, S Nap. 6) X single crystal structure analysis. For ， didn't get S Bi 6 and the single crystal 6 -- and S Ph couldn't do that. ， 2 in Fig. 2 aggregation structure of the complexes were obtained at the crystallographic data shown in Table 2. Combined with the analysis results of the A Nap 667. At the A -- Ph 664 shown. At the S -- Nap chiral complexes with heavy atom method applied to the analysis of ，The absolute structure was determined. As a result of ， is determined by the molecular structure is obtained in S body S Nap. 6.