金属錯体は無機物の性質をもつ金属イオンと有機物の性質をもつ有機配位子を

金属錯体は無機物の性質をもつ金属イオンと有機物の性質をもつ有機配位子
を組み合わせた化合物である。そのような金属錯体は，有機物と無機物の両方
の性質を兼ね備えた材料として，発光などの光機能，光電変換などの電子機能，
触媒機能，磁気機能といった多岐に亘る機能の発現が期待できるため，さまざ
まな分野で応用されている1-20。これらの機能の中でも，本研究では金属錯体の
発光特性に着目し，金属中心の電子的環境や分子凝集構造を制御することによ
って，多様な発光特性を有する材料の創製が可能であると考えた。
遷移金属錯体の多彩な性質は，遷移金属イオンの最外殻のd 軌道に充填され
た電子遷移に由来している。可視光領域に吸収をもつ遷移金属錯体の金属中心
は空のd 軌道を有するため，励起光を照射するとd 軌道間で電子が遷移（d-d 遷
移）し，励起状態へと達する。そして，例えば赤色や緑色の有機EL 素子として
開発されたイリジウム錯体は，励起状態から基底状態へと緩和が起こる際に吸
収したエネルギーを発光として放出する。このような遷移金属錯体は，従来の
有機蛍光物質に比べて非常に高い発光量子収率を示すことが知られている21, 22。
このように，近年，遷移金属錯体は発光性錯体として特異な光化学挙動を示す
ことが明らかにされている。特に最近では，銅，銀，白金，金イオンを有する
遷移金属錯体が，リン光発光を示す有機金属錯体として非常に注目を集めてい
る。

ผลลัพธ์ (อังกฤษ) 1:

Is metal complexes with metal ions with the nature of the inorganic and organic ligands.Combination of compound. Such as metal complexes, both organic and inorganic substances.For as nature materials, optical, electronic features such as photoelectric conversion, such as light-emittingCatalyst, which is the expression of the magnetic features on a wide range of features, customers.1-20 has been applied in different areas. Among these features, in this study of metal complexesBy controlling the molecular aggregation structure and the electronic environment of the metal Center, focusing on emissionI, and the creation of materials with various light-emitting characteristics should be considered.Transition metal ion LCFs d orbital filled with various properties of transition-metal complexesComing from he electronic transition. Metal heart of transition metal complexes absorption in the visible light rangeThe electronic transition among the d orbital to illuminate the excitation light to have empty d orbital, and (d-d transonicShifter), and reach to the excited state. And, as for example red or green organic ELECTROLUMINESCENT devicesIridium complexes has been developed, from the excited state to the ground state relaxation happens when intakeHigh yielding emit energy as light. These transition metal complexes, traditionalIs known that organic fluorescent materials compared to the very high quantum yield 21, 22.Thus, in recent years, transition metal complexes luminous complexes novel photochemical behavior refers to asIt has been revealed. Especially nowadays, with copper, silver, Platinum, gold ionsOrganometallic transition metal complexes show phosphorescence emission attracting attention very not.

ผลลัพธ์ (อังกฤษ) 2:

Metal complexes of organic ligands with the nature of the metal ions and organic matter having a property of inorganic
are compounds combining. Such metal complexes, both organic and inorganic materials
as a material having both properties, optical functions such as light emission, electronic features such as photoelectric conversion,
since the catalytic function, the expression of functions A wide variety such as a magnetic feature can be expected, Sama-za
1-20 has been applied in the Mana field. Among these functions, in the present study of the metal complex
is focused on light emitting property, by the controlling the electronic environment and molecular aggregation structure of the metal centers
I are possible creation of materials with diverse emission characteristics It was considered.
Colorful nature of the transition metal complex is filled to the d-orbit of the outermost shell of the transition metal ion
is derived from the electronic transition it was. Metal centers of transition metal complexes having an absorption in the visible light region
because it has an empty d-orbital, electrons between when irradiated d orbitals excitation light transition (dd Qian
to move), reaching into the excited state. Then, for example, as the red and green organic EL elements
iridium complex has been developed, intake when the place is relaxed from an excited state to a ground state
to emit energy to yield a light emission. Such transition metal complexes are conventional
to exhibit a very high emission quantum yield compared to the organic fluorescent materials are known 21, 22.
Thus, in recent years, the transition metal complexes show peculiar photochemical behavior as luminescent complexes
have been shown to be. Recently, in particular, copper, silver, platinum, has a gold ion
is a transition metal complex, has attracted much attention as organometallic complexes which exhibit phosphorescence
that.

ผลลัพธ์ (อังกฤษ) 3:

Compounds with organic ligands and metal ions on the properties of metal complexes with the properties of inorganic to organic matter. ， metal complexes such as material and is equipped with the properties of both inorganic and organic light emitting ， functions such as catalyst ， 3h-prolin electronic functions, such as a photoelectric conversion ， for ， and magnetic function expression can be expected from a variety of functions, such as applied in one's field at her first 20. ， among these functions, this study focused on the luminescent properties of metal complexes of ，You can control the structure of molecular aggregation of metal and the electronic environment ， out a variety of materials and fabrication of light emitting characteristics. ， various properties of transition metal complexes in the outermost d-orbital electrons of transition metal ions in the transition from. For ， having metal centers of transition metal complexes with absorption in the visible light region of empty d-orbitals between d-orbital electron irradiation with excited light transition (transition shift at (d) ， reaches to the excited state. For example, the ， organic EL element with red and green.， iridium complexes developed in relaxation and emission from the excited state to the ground state energy and light absorption at high yield. ， transition metal complexes as is known to exhibit a very high luminescence quantum yield as compared with the conventional organic fluorescence materials at the, 21, 22. In this ， recently ， transition metal complex and luminescent complexes at the photochemical behavior are revealed. Copper, silver, platinum ， ， ， ， recently that ， transition metal complexes with metal ionsAt you as a metal organic complexes phosphorescent emission has attracted much attention.