ベンゼン環は1 位と4 位，ビフェニル骨格は4 位と4’位，ナフタレン

ベンゼン環は1 位と4 位，ビフェニル骨格は4 位と4’位，ナフタレン環は2
位と6 位の炭素の距離を長軸の分子長とした。またベンゼン環では3 位から5
位，ビフェニル骨格は3’位から5’位，ナフタレン環は4 位から8 位の炭素に向
けて垂線を引き，その距離を短軸の分子長としてアスペクト比を算出した。図
2-8 より，アスペクト比の小さなベンゼン環（アスペクト比1.2）を有するS-Ph6
は液晶相を示さないが比較的低い融点を有することがわかった。一方，アスペ
クト比の大きなビフェニル骨格（アスペクト比3.0）を導入したS-Bi6 は降温過
程で約100 °C という幅広い温度範囲でN*相を発現することがわかった。そこで，
これらの錯体の中間のアスペクト比を有するナフタレン環（アスペクト比1.7）
を有するキラルなS-Nap6 が，室温付近かつ幅広い温度範囲でN*相を発現でき
る分子骨格だと考えた。この錯体S-Nap6 は，当初の予想通り，エナンチオトロ
ピック液晶性を示し，降温過程では室温付近までN*相を発現した。これらの結
果から錯体の相転移挙動はコア部位のアスペクト比と柔軟鎖の構造に強く影響
を受けることが明らかとなった。

ผลลัพธ์ (อังกฤษ) 1:

1st place and 4th place a benzene ring, biphenyl skeleton was fourth and 4 ' 2's, naphthaleneMolecular length of the major axis was ranked the sixth-largest carbon distance. Also in the benzene ring 5 from thirdThe biphenyl skeleton, 3 ' from 5 ' from carbon 8 position to fourth place, naphthaleneDraw perpendicular lines], distance calculate the aspect ratio as the molecular length of the minor axis. FigureThan 2-8, with tiny benzene rings of aspect ratio (aspect ratio 1.2) S-Ph6That could indicate a liquid has a relatively low melting point. On the other hand, Asperger'sS-Bi6 introduced the biphenyl skeleton large aspect ratios (aspect ratio 3.0) is the descending temperature overloadAs can develop the N * phase in a wide temperature range of 100 ° C is found. There,Aspect ratio in the middle of these complexes with naphthalene (aspect ratio 1.7)Chiral S-Nap6 have appeared, N * phase at room temperature and a wide temperature range can beI think that according to molecular skeleton. Coordination S-Nap6, initial expectations Street, enanthiothroCrystalline picks showed expressed the N * phase up to room temperature in the cooling processes. These resultsFrom fruit complex phase transition behaviour is strongly affect the structure of the aspect ratio of the core areas and flexible chainThat became clear.

ผลลัพธ์ (อังกฤษ) 2:

Benzene rings 1 and 4 positions, biphenyl skeleton 4 position and 4 'position, naphthalene ring 2
was the distance of the position and the 6-position of the carbon and molecular length of the long axis. The 5 from third place in the benzene ring
position, biphenyl skeleton 3 'place from the 5' position, naphthalene ring is directed to the carbon of position 8 from the 4-position
draw a vertical line to Ke, the aspect ratio the distance as the molecular length of the short axis It was calculated. Figure
from 2-8, S-Ph6 with small benzene ring aspect ratio (aspect ratio 1.2)
does not exhibit a liquid crystal phase but it was found to have a relatively low melting point. On the other hand, Aspect
S-Bi6 which introduced a large biphenyl skeleton of the defect ratio (aspect ratio 3.0) is lowered over
were found to express the N * phase in a wide temperature range of about 100 ° C in degree. Accordingly,
naphthalene ring (aspect ratio 1.7) having an intermediate aspect ratio of these complexes
are chiral S-Nap6 having, can express N * phase at around room temperature and a wide range of temperatures
was think molecular skeleton Ru. This complex S-Nap6 initially as expected, Enanchiotoro
shows a pick liquid crystallinity, expressed the N * phase to around room temperature in the cooling process. The binding
phase transition behavior of the complex from the results is strongly influenced by the structure of the aspect ratio and the flexible chain of the core portion
was found to undergo.

ผลลัพธ์ (อังกฤษ) 3:

The benzene ring 1 and 4 ， biphenyl skeleton 4 and 4 '- position ， naphthalene ring 2 and 6 of the carbon molecular long axis length and distance. The benzene ring 3 from 5 at the position ， 3 '5' position from the skeleton ， biphenyl naphthalene ring 4 from the perpendicular direction to pull up at the eighth largest carbon ， distance was calculated and the aspect ratio of the minor axis length. Fig. 2 8 ， small aspect ratio (aspect ratio) 1.2 benzene ring having at S Ph 6.It has a relatively low melting point liquid crystal phase (not shown). On the other hand ， large aspect ratio at the cult 3.0 biphenyl skeleton (aspect ratio) is introduced. S Bi 6 at the temperature over about expressing N phase in a wide temperature range of about 100. Degree. C. Then, at the ， naphthalene ring having an aspect ratio of these intermediate complexes with a chiral 1.7 off (including the aspect ratio and S Nap 6 near the room temperature and in a wide range can ， expression N phase at the molecular skeleton.This S complexes and Nap 6 ， originally expected ， ， show at the liquid crystal エナンチオトロ pick with N phase in the process of lowering temperature to room temperature. From these formation at the fruit and it became clear that the aspect ratio of the core region is strongly influenced by the flexible chain structure and phase transition behavior of the complexes.