また本研究室では，図1-5 に示す環状三核金錯体が，温度変化に伴って発

また本研究室では，図1-5 に示す環状三核金錯体が，温度変化に伴って発光色
が変化するサーモクロミズム特性を示すことを報告している53。この金錯体は
結晶相において，室温で紫色の発光を示し，この発光はAu-π 相互作用に起因す
る発光であることを見出した。さらに，この錯体は加熱によって凝集構造が変
化し，Au-π 相互作用に加えて親金相互作用を発現した黄色発光，そして赤色発
光へと可視光領域全般に渡った発光挙動を示す。さらに，この錯体は溶媒蒸気
にさらすことにより発光色が変化するベイポクロミズム特性も併せもつ。すな
わち，加熱によって赤色発光を示すようになった錯体は，ジクロロメタン蒸気
にさらすことで，黄色発光を示す凝集状態を経由して，はじめの紫色発光を示
す凝集状態に戻ることが報告されている。
このように有機分子を導入した金錯体は，熱相転移や機械的または化学的刺
激を外部から加えることで，容易に凝集構造変化を誘起し，発光色を可逆的に
制御できることから，優れた発光材料として期待がもてる。

ผลลัพธ์ (อังกฤษ) 1:

Also ring 3 gold complexes in the laboratory, shown in Figure 1-5's, Luminescent color with temperature changes53 to indicating the thermochromic properties to change the report. Gold complexesCrystal phases, showed purple luminescence at room temperature, this emission is due to the AU-π interactionWas found to be emitting. This complex structural change by heatingEqualized, in addition to the AU-π-interactions between parents expressing interaction gold yellow light, and red fromIndicate the light emission behavior to the light in the visible light region General crossed. In addition, this complex is the solvent vaporIn both even-70 vapochromism properties light color changing risk. IEDone, by heating was shown red luminous complexes is dichloromethane vapor.In the show, including purple light to over aggregation status shows yellow light, to expose theTo have been reported back to the States.Introduced organic gold complexes, thermal phase transitions, mechanical or chemical stingsBy adding external Super easily induced aggregation structure, emitting color reversiblyHave a hope for light-emitting materials that can be controlled.

ผลลัพธ์ (อังกฤษ) 2:

In this laboratory, cyclic three neutron gold complexes shown in Figure 1-5, the emission color with temperature change
is being reported to exhibit thermochromic characteristics are changed 53. The gold complex
in the crystal phase, and showed a light emission of the violet at room temperature, the light emission is attributable to the Au-π interaction
was found to be emitting want. In addition, this complex aggregation structure change by heating is
turned into, Au-π interaction in addition yellow light expressed Oya-kin interact, and red departure
shows the emission behavior across the visible light region in general and to the light. Furthermore, the complex solvent vapors
has also to vapochromism characteristic emission color is changed by exposure to. Sand
Wachi, complexes were to exhibit red light emission by heating are dichloromethane vapor
and by exposure to, via the aggregation state indicating the yellow light, the beginning of violet emission is shown
reported back to the nest aggregation state that has been.
The gold complex introduced with organic molecules as described above, the thermal phase transitions, mechanical or chemical puncture
By adding intense external and induces a readily aggregate structure changes, the emission color reversibly
because it can control, good expected I Moteru as light-emitting material.

ผลลัพธ์ (อังกฤษ) 3:

In this lab ， ， cyclic trinuclear complex shown in Fig. 1-5 reported that shows the characteristic emission thermochromism varying with the temperature change of color. In ， crystal phase in this complex ， shows purple emission at room temperature, it was found that the emission of luminescence due to Au pi interaction. In addition ， complex heat aggregated structure of yellow luminescence in at ， ， expressed parent interactions in addition to Au. PI. Interaction and departure at the redIn the visible light region to the whole light emission behavior. Even with this complex is also ， vapochromism changes color by the exposure to solvent vapor. That is at or ， ， became complex heating as shown in red by exposure to a light emitting ， dichloromethane vapor at via coagulation state in the yellow light ， reported that luminescence of aggregation index at first to return to the state. The gold complexes with organic molecules ， stab at this chemical mechanical or thermal phase transitionTo make an exhaustive ， externally induced structure changes can be easily ， ， control in reversible luminescent color can be expected as a luminescent material.