d10 遷移金属錯体の中でも，金(I)錯体は発光性遷移金属錯体としてデ

d10 遷移金属錯体の中でも，金(I)錯体は発光性遷移金属錯体としてディスプレ
イや化学センサーなどへの応用が期待されている29-35。金錯体は分子凝集系で強
い発光を示すことから，固体発光デバイスへの展開も期待できる。このような
発光性金属錯体には，金(I)以外にも銀(I)や銅(I)などの金属イオンを有するもの
も報告されている。重原子イオンを含む錯体は，分子内の誘起磁気モーメント
が大きくなるため，電子と原子核の磁気的相互作用に基づくスピン-軌道相互作
用も大きくなり，励起三重項を形成しやすくなる（重原子効果）。分子が発光
する過程には，励起一重項状態からの蛍光と励起三重項状態からのリン光があ
り，電界発光においてはそれぞれの励起子の生成確率は原理的に1 : 3 であるこ
とが知られている。そのため，蛍光発光材料は生成した全励起子のうち，発光
に関与するのは最大でも25 %である。一方，一重項に加えて三重項励起子から
も発光が起こるリン光発光材料の場合は，内部量子効率が原理的には最大100 %
に達することが可能になるため，蛍光材料に比べて高い発光効率を示す。発光
性遷移金属錯体のなかでも，金を用いた錯体は銀や銅を用いた場合よりも金属
間相互作用が強く，安定に錯体を形成する傾向がある。また，金錯体の発光は
錯体間の分子間相互作用に起因することが知られており，金錯体間にはたらく
主な相互作用として，金原子同士の親金相互作用と金原子とπ 共役分子による
Au-π 相互作用が挙げられる36-46。

ผลลัพธ์ (อังกฤษ) 1:

in D10 transition-metal complexes, gold (I) complexes is display as a luminous complexes.(A) and 29-35 are expected to chemical sensors. Gold complexes was strong in molecular aggregatesNot show emission can expect also to solid state light emitting device. Like thisLuminescent metal complexes with metal ions such as copper (I) and silver (I) (I) non-Also have been reported. Complexes containing heavy atoms is induced magnetic moment in a molecule., Based on the magnetic interaction between electron and nuclear spin-orbit interaction worksFor larger, easier to form a triplet excited (heavy-Atom effect). Emitted by molecularIn the process, phosphorescence, fluorescence from the excited Singlet State and the excited triplet State.And, in the emission probability of each is the 1:03 principle.There are known. Therefore, all excitons generated among light fluorescent light-emitting materialsIn involved in 25% at most. On the other hand, in addition to the singlet triple section excitation from the childAlso in principle, internal quantum efficiency phosphorescent light emitting material emission will happen when up to 100%On the show, because that can be compared to the fluorescent material high luminous efficiency. Light-emittingThan when using silver and copper complexes of transition metal complexes of gold metal.While tend to interact, forming a stable complex. In addition, emission of gold complexesGold complexes while working, due to a molecular interaction between the complexes is knownAs the main interaction, money to child-parent interaction between gold and gold with π-conjugated moleculesAu-π interaction is 36-46.

ผลลัพธ์ (อังกฤษ) 2:

d10 Among the transition metal complexes, gold (I) complexes display a luminescent transition metal complexes
stomach and applications such as chemical sensors are expected 29-35. Gold complex strength at the molecular aggregation system
from that show has emission, can be expected deployment to the solid-state light-emitting device. Such
the luminescent metal complexes, having a metal ion such as gold (I) of silver in addition to (I) or copper (I)
have also been reported. Complex containing a heavy atom ions induced magnetic moment of the molecule
for larger spin based on magnetic interaction of electrons and atomic nuclei - orbit interaction
also increases for, easily form a triplet (heavy atoms effect). Molecules emission
in the course of, excited phosphorescence there from the fluorescent and excited triplet state from the singlet state
is, each generation probability of excitons in principle in electroluminescent 1: 3 Dearuko
and is Are known. Therefore, among all excitons fluorescent light-emitting material has been produced, the emission
is 25% at maximum to participate in. Meanwhile, the triplet excitons in addition to the singlet
case of phosphorescent light-emitting material emission also occurs, the internal quantum efficiency of up to 100% in principle
since it is possible to reach, and higher than the fluorescent material It shows the luminous efficiency. Emitting
Among transition metal complexes, complexes with gold metal than the case of using silver or copper
strong interaction, stable tend to form a complex. In addition, light emission of the gold complexes
are known to be due to intermolecular interactions between the complex, acting between the gold complex
as the main interactions, Oya-kin interacts with the gold atoms and the π-conjugated molecules between gold atoms According to the
36-46 that Au-π interaction and the like.

ผลลัพธ์ (อังกฤษ) 3:

In ， D10 transition metal complexes of gold (I 29-35 are expected at the display and a chemical sensor applications such as luminescent transition metal complexes. ， from gold complexes in polymer systems shows that can be expected at the emission of light emitting devices. Luminescent metal complexes at the ， such money. But it I silver or copper. I I at with some metal ions, such as has been reported. The ， complexes containing heavy metallic ions for ， induced magnetic moment in the larger molecules.As for the large spin-orbit interaction. Based on the magnetic interaction of electrons and nuclei become excited ， multiplets, easy formation of a heavy atom effect). In the process of ， molecular phosphorus light. "I ， from fluorescence and excited triplet state from the excited singlet state light field in the generation probability of each of the exciton in principle known as" 1. 3. For all its ， excitons generated in the ， fluorescent material is involved in the largest emission at 25. On the other hand ，， of phosphorescent material in addition to the singlet; from the triplet exciton emission occurs at the ， becomes possible in principle, the internal quantum efficiency can reach up to 100 don't do exhibiting high luminous efficiency compared with fluorescent materials. Luminescence properties of transition metal complexes ， strong interactions between metal ， than silver or copper complexes with money tend to form stable complexes. The ， ， known to be due to intermolecular interactions between the complexes of gold at the complex interaction between metal complexes.Interaction as the main ， include Au pi interaction by. PI. - conjugated molecules and atoms of gold gold gold atoms and the interaction between 36 and 46.