Au-π 相互作用は，フェニル基のような電子豊富な芳香環と金(I)イオ

Au-π 相互作用は，フェニル基のような電子豊富な芳香環と金(I)イオンとの間
にはたらく相互作用のことである。一般に，金(I)イオンと芳香環中心との距離
が4.0 Å 以下に接近したとき，かつ芳香環に垂直な軸に対して金(I)イオンと芳香
環中心のなす角度が20 °以下の時に，Au-π 相互作用が発現すると報告されてい
る。この相互作用は金(I)イオンだけでなく金(III)イオンでも発現することが知ら
れており，結晶中においてAu-π 相互作用がはたらくことで，金属錯体は安定な
凝集構造を形成することが明らかとなっている。そのため，親金相互作用とと
もにAu-π 相互作用は，新規な超分子凝集体や結晶中での凝集構造を形成するた
めの駆動力となる可能性があるとして，注目を集めている。

ผลลัพธ์ (อังกฤษ) 1:

Au-π interaction is between AU (I) ions and electron-rich aromatic ring such as phenyl group.In that interaction work. In General, gold (I) ions and aromatic ring Centre away.When approached to 4.0 Å, and axes are perpendicular to the aromatic ring (I) ions and aromaticThe ring around the angle at the time of less than 20 ° au-π interactions have been reported. This interaction as well as gold (I) ions, expressed in gold (III) ions are knownAlso, works au-π-interactions in crystals by metal complexes are stableTo form a cohesive structure has become apparent. Therefore, parents and money interactionAlso in the AU-π-interactions of novel supramolecular aggregates and had to form a cohesive structure in CrystalOrder of may be the driving force, has attracted attention.

ผลลัพธ์ (อังกฤษ) 2:

Au-π interaction between the electron-rich aromatic ring and a gold (I) ions, such as phenyl group
is that of the interaction acting. In general, the distance between the gold (I) ion and the aromatic ring center
is 4.0 Å when the approaches to, and with respect to an axis perpendicular to the aromatic ring of gold (I) ions and aromatic
angle between the ring center than the 20 ° Sometimes, it has been reported that Au-π interaction is expressed
that. This interaction is known to be expressed in gold (III) ions as well as gold (I) ions
are, by Au-π interaction works in the crystal, the metal complex is stable
to form a cohesive structure It has been revealed. Therefore, Oya-kin interact with and
monitor Au-π interaction has the form aggregated structures in a novel supramolecular aggregates or crystals
as may become a driving force of the eye, drawing attention there.

ผลลัพธ์ (อังกฤษ) 3:

， π interaction Au electron-rich aromatic rings and the like of the phenyl group of I is at work in the mutual action between the ions. In general ， gold I. ， when the center distance of the aromatic ring and close to the ion 4.0 gold and a vertical axis with respect to the aromatic ring and I. The angle at the center of the aromatic ring at the time of less than 20. Degree in ， ions and to report. Au. PI. Interaction and expression. This money I interaction not only III gold ions that are expressed in the ion at the known and ，It works in Au ， π interactions in the crystal clear that a stable metal complex structure is formed. Therefore ， ， Au π interaction and interaction with parents' money and there is a possibility that the new crystal in supramolecular aggregates, and the driving force of the aggregation structure is formed at the ， has attracted attention.